아닐린 합성실험(Synthesis of Aniline ) - 산화환원 합성

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"아닐린 합성실험(Synthesis of Aniline ) - 산화환원 합성"에 대한 내용입니다.

목차

1. Title
2. Objective
3. Theoretical Background
4. Apparatus & Reagent
5. Experimental Procedure
6. Pre-Lab report
7. Reference

1. Result
2. Discussion
3. Report
4. Summary
5. Reference

본문내용

1. Title: Synthesis of Aniline
2. Objective
Prepare aniline from nitrobenzene using iron and hydrochloric acid, and understand the principle of the amination reaction, one of the reactions of various organic compounds.
3. Theoretical Background
1) Reduction
Let's look at the meaning of reduction, an aniline synthesis method. First of all, reduction in the dictionary sense refers to a chemical change that returns an oxidized material to its original state. In a general narrow sense, it refers to the case where hydrogen is applied or oxygen is given, but broadly, it is said to have been reduced when electrons are obtained. In summary, the reaction of obtaining electrons, the reaction of obtaining hydrogen, the reaction of breaking bonds with oxygen, and the reaction of decreasing oxidation number are reduction reactions.

참고 자료

[Experimental procedure] “Chemical Engineering Laboratory I”, Sungkyunkwan University School of Chemical Engineering
https://safety.skku.edu/ - MSDS
Stergiou AD, Broadhurst DH, Symes MD. Highly Selective Electrocatalytic Reduction of Substituted Nitrobenzenes to Their Aniline Derivatives Using a Polyoxometalate Redox Mediator. ACS Org Inorg Au. 2022 Nov 21;3(1):51-58. doi: 10.1021/acsorginorgau.2c00047. PMID: 36748077; PMCID: PMC9896480.
Stergiou AD, Broadhurst DH, Symes MD. Electrochemical reduction of nitrobenzene via redox-mediated chronoamperometry. STAR Protoc. 2022 Nov 4;3(4):101817. doi: 10.1016/j.xpro.2022.101817. PMID: 36386882; PMCID: PMC9641269.
Paluch J, Kozak J, Mermer K, Molęda I, Wieczorek M, Kalinowski S, Kościelniak P. Novel Integrated Flow-Based Steam Distillation and Titration System for Determination of Volatile Acidity in Wines. Molecules. 2021 Dec 18;26(24):7673. doi: 10.3390/molecules26247673. PMID: 34946754; PMCID: PMC8708693.
[Experimental procedure] “Chemical Engineering Laboratory I”, Sungkyunkwan University School of Chemical Engineering
https://safety.skku.edu/ - MSDS
Stergiou AD, Broadhurst DH, Symes MD. Highly Selective Electrocatalytic Reduction of Substituted Nitrobenzenes to Their Aniline Derivatives Using a Polyoxometalate Redox Mediator. ACS Org Inorg Au. 2022 Nov 21;3(1):51-58. doi: 10.1021/acsorginorgau.2c00047. PMID: 36748077; PMCID: PMC9896480.
Stergiou AD, Broadhurst DH, Symes MD. Electrochemical reduction of nitrobenzene via redox-mediated chronoamperometry. STAR Protoc. 2022 Nov 4;3(4):101817. doi: 10.1016/j.xpro.2022.101817. PMID: 36386882; PMCID: PMC9641269.
Paluch J, Kozak J, Mermer K, Molęda I, Wieczorek M, Kalinowski S, Kościelniak P. Novel Integrated Flow-Based Steam Distillation and Titration System for Determination of Volatile Acidity in Wines. Molecules. 2021 Dec 18;26(24):7673. doi: 10.3390/molecules26247673. PMID: 34946754; PMCID: PMC8708693.
John McMurry. Organic Chemistry 9th. 2015 Mar 25. ISBN-13: 978-130508048
Malcolm P. Stevens. Polymer Chemistry - An Introduction. 2009. ISBN: 978-0195392098