서울대학교 유기무기실험 - Synthesis and Metalation of Porphyrin (9번째)

소개

"서울대학교 유기무기실험 - Synthesis and Metalation of Porphyrin (9번째)"에 대한 내용입니다.

개강 후 9번째 실험입니다
(무기 3번째, 마지막 실험)

목차

1. Abstract
2. Introduction
3. Materials and Methods
4. Experimental Procedure
5. Results
6. Discussion
7. Conclusion
8. References

본문내용

Abstract
In this experiment, we foucsed on the synthesis of porphyrin and metalation of it. On day 1, we focused on synthesizing porphyrin, understanding its features. On day 2, we metalated porphyrin synthesized on day1. Afterwards, we performed various spectroscopic measurements, such as NMR or UV-vis to understand the features of macrocyclic compounds.
Introduction
The major content of this experiment is about porphyrin. What is porphyrin? Porphyrin is a macrocyclic molecule that consists of four pyrrole rings (See Figure S1). Porphyrin is aromatic and it contains 22 π electrons, 18 of them participating in conjugation. Porphyrin, at the center, has 4 nitrogen atoms, which can coordinate a metal ion.

참고자료

· Morten K. Peters; Rainer Herges Inorg. Chem. 2018, 57, 3177–3182.
· J. S. Lindsey; Irwin C. Schreiman; Henry C. Hsu; Patrick C. K.; Anne M. Marguerettaz J. Org. Chem. 1987, 52, 827–836.
· T. E. Shubina; H. Marbach; Ken Flechtner; A. Kretschmann; N. Jux; F. Buchner; Hans-Peter Steinruck; T. Clark; J. M. Gottfried J. Am. Chem. Soc. 2007, 129, 9476–9483.
· Gary L. Miessler; Paul J. Fischer; Donald A. Tarr Inorganic Chemistry, 5th Edition; Pearson, 2014.
· J. E. Falk; Kevin M. Smith Porphyrins and Metalloporphyrins; Elsevier, 1975.